4.7 Article

Synthesis of Functionalized Dihydrothiophenes from Doubly Activated Cyclopropanes Using Tetrathiomolybdate as the Sulfur Transfer Reagent

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 2, Pages 700-703

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo102059p

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Funding

  1. Council of Scientific and Industrial Research (CSIR), New Delhi

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A number of doubly activated cyclopropanes were synthesized starting from various substituted bromosulfonium bromides in good yield. Regioselective ring-opening of cyclopropanes with tetrathiomolybdate as the sulfur transfer reagent gave dihydrothiophenes in excellent yield.

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