Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 15, Pages 6286-6294Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo2010704
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Funding
- Ministerio de Ciencia e Innovacion
- FEDER [CTQ2009-13083]
- Generalitat Valenciana [ACOMP/2011/267]
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Chiral complexes of 1,1'-bi-2-naphthol-based ligands with zirconium tert-butoxide catalyze the Friedel Crafts alkylation of pyrroles with alpha-ketoesters to afford tertiary alcohols in good yields and ee up to 98%. The reaction is also of application to 4,7-dihydroindole to give C2-alkylated indoles after oxidation with p-benzoquinone.
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