Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 4, Pages 1174-1176Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo1023377
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Funding
- National Institutes of Health [GM-46059, 1F32GM093532]
- EMD Serono
- Martin Family Society of Fellows for Sustainability
- National Science Foundation (NSF) [CHE-9808061, DBI-9729592]
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A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boronic acids has been developed. This protocol is amenable to normal benchtop setup and reactions typically require only 1-4 h. Proceeding under mild conditions, the method tolerates a range of functional groups, allowing access to a variety of trifluoromethylarenes.
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