Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 20, Pages 8466-8471Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo2010022
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Funding
- Department of Atomic Energy, Government of India
- CSIR
- DST
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A rapid synthetic route for polyarylated boron-dipyrromethenes using hexabromo boron-dipyrromethene as the key synthon is described. The X-ray structure revealed that the polyarylated BODIPY adopts a propeller-like conformation. These compounds exhibit red-shifted absorption and fluorescence bands with decent quantum yields and reversible oxidation and reduction waves when compared to unsubstituted boron-dipyrromethenes.
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