Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 1, Pages 277-280Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo101504e
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A trichloroisocyanuric acid (TCCA) mediated Hofmann rearrangement was utilized to synthesize methyl-1-(tert-butoxycarbonylamino)-2-vinylcyclopropanecarboxylate. A variety of functional groups are tolerated in this reaction including vinyl, cyclopropyl, pyridyl, atyl, benzyl, and nitro groups.
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