Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 18, Pages 7569-7572Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201213e
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- MIUR
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A new water-soluble uranyl-salophen complex incorporating two glucose units has been synthesized. This neutral derivative shows noteworthy binding affinity for fluoride in water thanks to the Lewis acid base interaction occurring between the metal and the anion. Such interaction is strong enough to overcome the high hydration enthalpy of fluoride. Moreover this complex effectively binds hydrogen phosphate and exhibits remarkably strong association for nucleotide polyanions ADP(3-) and ATP(4-).
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