4.7 Article

Hydrogen Bonding-Directed Quantitative Self-Assembly of Cyclotriveratrylene Capsules and Their Encapsulation of C60 and C70

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 9, Pages 3531-3535

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo102577a

Keywords

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Funding

  1. MOST of China [2007CB808001]
  2. NSFC [20732007, 20921091, 20872167, 20974118]
  3. STCSM [09 XD1405300]

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Under the direction of intramolecular three-center hydrogen bonding, two cyclotriveratrylene (CTV)-based capsules are assembled quantitatively from C-3-symmetric CTV precursors by forming three imine bonds from arylamide-derived foldamer segments. H-1 and C-13 NMR and UV/vis experiments reveal that the capsules strongly encapsulate C-60 and C-70 in discrete solvents.

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