Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 18, Pages 7370-7376Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201030j
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- Okayama University
- Grants-in-Aid for Scientific Research [22245017, 21750103] Funding Source: KAKEN
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Dibenzophosphole oxides were obtained from secondary hydrophosphine oxides with a biphenyl group by dehydrogenation via phosphine hydrogen and carbon hydrogen bond cleavage in the presence of a catalytic amount of palladium(II) acetate, Pd(OAc)(2). By using this reaction, a ladder-type dibenzophosphole oxide could also be synthesized by double intramolecular dehydrogenative cyclization.
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