4.7 Article

Common Origin, Common Fate: Regular Porphyrin and N-Confused Porphyrin Yield an Identical Tetrapyrrolic Degradation Product

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 24, Pages 9956-9961

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo201489z

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Funding

  1. Ministry of Science and Higher Education [N N204 021939]

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The formation of an identical linear tetrapyrrole observed in the course of photooxidation of meso-tetraarylporphyrin and its N-confused isomer can be explained as a result of 1,2- and 1,3-dioxygen addition, respectively, as substantiated by DFT calculations.

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