Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 22, Pages 9444-9451Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201822k
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Funding
- National Natural Science Foundation of China
- Science and Technology Commission of Shanghai Municipality
- Education Commission of Shanghai Municipality
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A series of enantiomerically pure gamma-heteroatom substituted beta-hydroxy esters were synthesized with high enantioselectivities (up to 99.1% ee) by hydrogenation of gamma-heteroatom substituted beta-keto esters in the presence of Ru(S)-SunPhos catalyst. These asymmetric hydrogenations provide key building blocks for a variety of naturally occurring and biologically active compounds.
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