Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 24, Pages 10229-10235Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo202152b
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- CSIR
- UGC New Delhi
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Regioselective iron-catalyzed cross-dehydrogenative coupling (CDC) of two aromatic compounds using tert-BuOOH as oxidant under mild conditions has been reported. The direct oxidative coupling reaction is selective toward creation of a carbon-carbon bond at the position ortho to the functional groups of the substrates, completely preventing the homocoupled products. The C-C bond-forming reaction makes the method versatile, leading to functionalized 2,2' -disubstituted biaryls.
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