Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 2, Pages 623-630Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo102208d
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Funding
- NIGMS [R01 GM086209, GM035249]
- Conselho Nacional de Desenvolvimento Cientitico e Tecnologico (CNPq)
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A method for the oxidation of organotrifluoroborates using Oxone was developed. A variety of aryl-, heteroaryl-, alkenyl-, and alkyltrifluoroborates were converted into the corresponding oxidized products in excellent yields. This method proved to be tolerant of a broad range of functional groups, and in secondary alkyl substrates it was demonstrated to be completely stereospecific.
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