4.7 Article

Tribenzotriquinacenes Bearing Six-Fold Benzofuran Extensions: Electron-Rich C3v-Symmetrical Hosts for C60

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 9, Pages 3231-3238

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo2000918

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Funding

  1. National Basic Research Program (973 Program) of China [2010CB833203]
  2. National Natural Science Foundation of China [20972060, 21061160494]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [20090211110007]
  4. 111 Project

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New tribenzotriquinacene (TBTQ) hosts bearing six-fold peripheral benzofuran functionalization have been synthesized. The three polycondensed arene wings were shown to operate optically independently and to generate deeply bowl-shaped C-3v-symmetrical frameworks that act as relatively weak hosts toward C-60, as revealed by H-1 NMR spectroscopy.

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