Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 17, Pages 7096-7103Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201064h
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Funding
- MEXT [2105]
- KAKENHI from the JSPS [22550115]
- Grants-in-Aid for Scientific Research [22550115] Funding Source: KAKEN
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The potential of the oxy-Favorskii rearrangement to form branched cis-fused bicyclic ethers was explored. Both tertiary and quaternary centers were constructed in highly stereospecific manners. Methanol and primary amines were effective nucleophiles for the rearrangement. The total synthesis of (+/-)-communiol E was achieved based on this method.
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