Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 1, Pages 257-260Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902292t
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Funding
- National Natural Science Foundation of China [20421202, 20672054, 2-0872073]
- III project [B06005]
- Committee of Science and Technology of Tianjin
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A reversible in situ acidic catalytic system comprising recyclable TEMPO functionalized imidazolium salt ([Imim-TEMPO][Cl])/NaNO2/CO2/H2O was developed for selective transformation of a series of aliphatic, allylic, heterocyclic, and benzylic alcohols to the respective carbonyl compounds. Notably, the system avoids any conventional acid and can eliminate unwanted byproducts, facilitate reaction, ease separation of the catalyst and product, and also provide a safe environment for oxidation involving oxygen gas.
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