Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 8, Pages 2726-2729Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100197r
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- Merck Frosst
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A room-temperature, copper-catalyzed amination of primary benzylic C-H bonds with primary and secondary sulfonamides is described. The reaction is applicable to the coupling of a range of primary and secondary benzylic hydrocarbons with a diverse set of sulfonamides and is tolerant of substitution on both coupling partners. Factors which influence the selectivity of C-H functionalization between primary and secondary sites are examined.
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