Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 3, Pages 856-863Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902413h
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Funding
- NRF [R-143-000-360281]
- NUS [R-143-000-356101]
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Three meso-substituted bisanthenes, 4-6, were prepared in a short synthetic route from the bisanthenequinone. They exhibit largely improved stability and solubility in comparison to the parent bisanthene. All of these compounds also show near-infrared (NIR) absorption and emission with high to moderate fluorescence quantum yields. Amphoteric redox behavior was observed for 4-6 by cyclic voltammetry, and these compounds can be reversibly oxidized and reduced into respective cationic and anionic species by both electrochemical and chemical processes. In addition, compound 5 adopts a herringbone pi-stacking motif in the single crystal.
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