Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 1, Pages 117-122Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902081w
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Funding
- National Natural Science Foundation of China [20172064, 203900502, 20532040]
- 973 Program
- Shangliai Natural Science Council
- Excellent Young Scholars Foundation of National Natural Science Foundation of China [20525208]
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Primary-secondary diamine catalysts were used to catalyze the asymmetric Robinson annulation to synthesize multiply substituted fluorinated chiral cyclohexenones with two contiguous stereogenic centers, one of which is a fluorinated quaternary chiral center, with excellent enantioselectivities and diastereoselectivities in moderate to good yields.
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