Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 18, Pages 6271-6274Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo1011448
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- School of Chemistry at the University of Nottingham
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A nucleophilic catalysis method providing a concise synthesis of di-, tri-, and tetrasubstituted pyrroles is described. This regioselective one-pot method relies on nucleophilic catalysis of the intermolecular addition of oximes to activated alkynes and thermal rearrangement of the in situ generated O-vinyl oximes to form pyrroles that contain a functional group handle at the C3/C4 position.
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