Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 16, Pages 5768-5771Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo101253a
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Funding
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20060335036]
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A copper-catalyzed cascade method has been developed to synthesize the 2H-benzo[b][1,4]thiazin-3(4H)-ones from 2-halo-N-(2-halophenyl)-acetamides 1 and AcSH via the S(N)2/deacetylation/coupling process, and to synthesize the quinoxalin-2(1H)-ones from 1 and TsNH2 via the S(N)2/coupling/desulfonation process. The target products were obtained with diversity at three positions on their scaffolds.
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