Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 9, Pages 2966-2970Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100247a
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Funding
- National Natural Science Foundation of China [20573061]
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DMF (N,N-dimethylformamide)/KOH was found to be an efficient hydrogen source in the Pd(OAc)(2)-catalyzed transfer semihydrogenation of various functionalized internal alkynes to afford cis-alkenes in good to high yields with excellent chemo- and stereoselectivity. This catalytic process was also applied to the synthesis of analogues of combretastatin A-4.
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