4.7 Article

Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine-and Phosphine-Boranes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 20, Pages 6983-6985

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo101301d

Keywords

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Funding

  1. US National Science Foundation UPMC, CNRS, [CHE-0645998]
  2. French Agence Nationale de la Recherche (ANR) [BLAN0309, 08-CEXC-011-01]
  3. NMR, MS [FR 2769]
  4. Direct For Mathematical & Physical Scien
  5. Division Of Chemistry [0956921] Funding Source: National Science Foundation

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A versatile new method for the preparation of NHC boranes starting from two stable readily available reactants-an heterocyclic salt and an amine phosphine-borane-is reported It uses a Lewis base exchange at boron and provides easy access to new NHC boianes in particular B-substituted borane ones

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