Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 17, Pages 6035-6038Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo101164a
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Funding
- National Nature Science Foundation of China [20802002, 20902004]
- Anhui Province [090416221, KJ2009A 130]
- Scientific Research Foundation Ministry
- Ministry of Education of China [2009342120001]
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A series of asymmetrical benzo-fused BODIPY dyes were synthesized from the Sonogashira coupling and nucleophilic substitution reactions on the 3-halogenated benzo-fused BODIPY, generated from readily available 3-halogeno-1-formylisoindoles in a two-step synthetic procedure. This novel BODIPY platform provides an easy path for the linking of BODIPY fluorophore to various desired functionalities as demonstrated in this work. Most of the resulting BODIPY dyes show long-wavelength absorption and fluorescence emission, with good fluorescence quantum yields and long fluorescence lifetimes.
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