Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 21, Pages 7400-7403Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100971j
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Funding
- Violet Olson Beltmann Fund
- Arnold and Mabel Beckman Foundation
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Clathculins A and B represent a new class of vic-diamine alkaloids containing a PA2 unit as the basic structure. We report the first total syntheses of 1 and 2, which confirm the assigned structure of each. Dependence of their NMR spectroscopic behavior as a function of protonation state has been observed.
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