Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 9, Pages 3117-3120Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100150s
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- Region Bretagne
- Agence Nationale de la Recherche
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Lithium cadmates bearing different ligands were compared with efficient (TMP)(3)CdLi (TMP = 2,2,6,6-tetra-methylpiperidino) for their ability to deprotometalate anisole. The generated arylcadmates were evidenced using I-2. The results show that it is possible to replace only one of the TMP (with a piperidino, a diisopropylamino, a butyl, or a sec-butyl) without important yield drop. In the light of DFT calculations, reaction pathways were proposed for the deprotocadmations of anisole using a triamino, an alkyldiamino, and an aminodialkyl cadmate.
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