Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 4, Pages 1087-1094Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo901923q
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Funding
- CSIR, New Delhi
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A cyclic tetrapeptide is prepared from alternating (S)-beta-Caa (C-linked carbo-beta-amino acid) and (R)-Ama (alpha-aminoxy acid). Extensive NMR (in CDCl(3) solution) and mass spectral (MS) studies show its halide binding capacity, with a special affinity to the chloride ion. At higher concentration it was found to form molecular aggregates its evidenced from transmission electron microscopic and atomic force microscopic analysis, confirming the formation of nanorods.
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