Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 1, Pages 241-244Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902180u
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Funding
- Czech Science Foundation [203/07/1302]
- Ministry of Education, Youth and Sports of the Czech Republic [1M 0508, MSM0021620822]
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Direct arylation and alkenylation of 1-substituted tetrazoles was achieved via Pd catalysis in the presence of CuI and CS2CO3. Unlike the related reactions of imidazoles and purines, phosphine ligand was necessary to prevent the intermediate tetrazolyl-Pd-II species from fragmentation into the corresponding cyanamide, Various 1,5-disubstituted tetrazoles were prepared with good to excellent isolated yields.
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