4.7 Article

Complexes of Ionic Liquids with Poly(ethylene glycol)s

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 6, Pages 1888-1891

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo902521w

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Funding

  1. National Natural Science Foundation of China [NSFC 20772110]

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The self-assembly behavior of ionic liquids with acyclic polyethers was studied. The cations of 1-alkyl-3-methylimidazolium salts and 1-alkylpyridinium salts could form complexes at a ratio of 1:1 with poly(ethylene glycol)-800 (PEG800) and poly(propyleneglycol)-1000 (PPG 1000) in which the chain length was suitable to wraparound the cations. On the basis of the investigation by NMR, mass spectrometry, UV-vis spectroscopy, and TG analysis, the formation and characteristics of the novel complexes were discussed.

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