4.7 Article

Impregnated Copper on Magnetite as Recyclable Catalyst for the Addition of Alkoxy Diboron Reagents to C-C Double Bonds

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 10, Pages 3458-3460

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo100325e

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Funding

  1. Spanish Ministerio de Ciencia y Tecnologia [Consolider Ingenio 2010 CSD2007-00006, CFQ2007-65218/BQU]
  2. Generalitat Valenciana [G.V. PROMETEO/2009/039]
  3. PROMETEO program

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A simple protocol for the borylation with use of impregnated copper on magnetite is described. The reactions showed a very broad scope and all type of olefins could be used with similar results. The catalyst could be easily removed by a magnet and it could be reused several times, showing similar activity.

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