Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 6, Pages 2061-2064Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902422y
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Funding
- Walther Cancer Institute, Circagen
- Ara Parseghian Medical Research Foundation
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The utility of the unsaturated phosphonate 1 its it vinylogous Horner-Wadsworth-Emmons reagent was explored in reactions with aldehydes affording 4-methyldienoate esters. Factors that affect E/Z selectivity were Studied. A simplified synthesis of trichostatic acid 3 was accomplished to demonstrate utility of this reagent.
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