Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 5, Pages 1733-1739Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100148x
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Various dihaloazoles can be monoarylated at a single C-X bond with high selectivity via Suzuki coupling. By changing the palladium catalyst employed, the selectivity can be switched for some dihaloazoles, allowing for Suzuki coupling at the other, traditionally less reactive C-X bond. These conditions are applicable to coupling of a wide variety of aryl-, heteroaryl-, cyclopropyl-, and vinylboronic acids with high selectivities and enable the rapid construction of diverse arrays of diarylazoles in a modular fashion.
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