Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 12, Pages 4025-4038Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100286r
Keywords
-
Categories
Funding
- Dutch Polymer Institute (DPI)
- Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO)
- Fonds der Chemischen Industrie
- Carl-Zeiss Stiftung
Ask authors/readers for more resources
New 2-[1H[1,2,3]triazol-4-yl)pyridine bidentate ligands were synthesized as bipyridine analogs, whereas different phenylacetylene moieties of donor and acceptor nature were attached at the 5-position of the pyridine unit. The latter moieties featured a crucial influence on the electronic properties of those ligands. The N-heterocyclic ligands were coordinated to ruthenium(II) metal ions by using a bis(4,4'-dimethy1-2,2'-bipyridine)ruthenium(II) precursor. The donor or acceptor capability of the 2-(1H[1,2,3]triazol-4-yl)pyridine ligands determined the quantum yield of the resulting ruthenium(11) complexes remarkably. Separately, 2-([1,2,3]triazol-4-yppyridine ligands are known to be potential quenchers, but using these new ligand systems led to room temperature emission of the corresponding ruthenium(I I) complexes. The compounds have been fully characterized by elemental analysis, high-resolution ESI mass spectrometry, H-1 and C-13 NMR spectroscopy, and X-ray crystallography. Theoretical calculations for two ruthenium(II) complexes bearing a donor and acceptor unit, respectively, were performed to gain a deeper understanding of the photophysical behavior.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available