Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 19, Pages 6673-6676Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo100905j
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Funding
- 973 Program [2006CB932900]
- NNSFC [20932004, 20721062, 20772063]
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Naphthyl-bridge bis(beta-cyclodextrin) (1) was synthesized via click chemistry, and its self-assembly behavior was investigated by NMR, UV-vis, circular dichroism spectra, transmission electron microscopy, and atomic force microscopy. The results obtained indicate that the coordination of Hg2+ with triazole rings in 1 induces the naphthyl moiety to move from being a self-included complex to the formation of nanoparticles through intermolecular self-aggregation. Furthermore, the formation and disassembly of nanoparticle was reversibly controlled by adding or removing Hg2+.
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