Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 75, Issue 11, Pages 3847-3850Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo1002938
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Funding
- NIGMS [NIH R01 GM068650]
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Alkylidenecyclopropanes can be synthesized from enantiomerically enriched cyclopropene derivatives with > 99% stereotransfer and good to excellent yield. The protocol comprises the stereoselective reaction of Grignard reagents with 1-alkoxymethyl-3-hydroxymethylcyclopropenes and a stereospecific [1,3] carbon shift reaction.
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