Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 23, Pages 9214-9217Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902018j
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Funding
- Science Foundation Ireland (SFI)
- Trinity College Dublin
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG)
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Improved catalyst design by incorporating a hydrogen bond donating substituent to improve enantiocontrol together with an acidifying pentafluorophenyl substituent to enhance catalyst efficiency results in a triazolium ion precatalyst that promotes the asymmetric archetypal benzoin condensation with excellent efficiency and unprecedented enantioselectivity.
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