Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 5, Pages 2197-2199Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo8026627
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- Scientific and Technological Research Council of Turkey (TUBITAK)
- Turkish Academy of Science (TOBA),
- Middle East Technical University (METU)
- Turkish State Planning Organization
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The first catalytic intermolecular aldehyde-ketone coupling via acyl phosphonate is reported. Acyl phosphonates are potent acyl anion precursors, which generate acyl anion equivalents under the influence of cyanide anion via phosphonate-phosphate rearrangement. These anions readily react with activated ketones to form acyloin type coupling in 41-95% yields.
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