Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 17, Pages 6797-6801Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo9012354
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Funding
- National Natural Science Foundation of China [20872163, 20872037, 20732008]
- Chinese Academy of Science, Science and Technology Commission of Shanghai Muncipality [07JC14063]
- Major State Basic Research Development Program [2006CB806105]
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An efficient, general, and one-pot procedure for the synthesis of multisubstituted xanthene derivatives through Fe(III)-catalyzed reactions of 2-aryloxybenzaldehydes with electron-rich arenes has been developed. This method offers several advantages such as high selectivities, mild reaction conditions, and easily accessible starting materials. A mechanistic study revealed that a C-C bond cleavage of a triarylmethane intermediate might be involved in the domino process.
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