Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 8, Pages 3168-3171Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo9001933
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A new class of discotics derived from tris(N-salicylideneaniline)s have been synthesized and their thermal and photophysical properties are investigated. These systems with outer 1,3,4-oxadiazole wings exist in an inseparable mixture of two keto-enamine tautomeric forms with C-3h and C-s rotational symmetries, and self-assemble into fluid columnar phase over a wide thermal range as evidenced by several complementary studies. They possess emissive characteristics in both solution and columnar states; the blue light (lambda = 474 nm) emission has been evidenced for the former state.
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