4.7 Article

Silver(I)-Catalyzed Cascade: Direct Access to Furans from Alkynyloxiranes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 11, Pages 4360-4363

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo900483m

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Funding

  1. CNRS
  2. French Ministry of Research

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Functionalized furans are conveniently formed by a new silver(I)-catalyzed reaction of alk-1-ynyl oxiranes in the presence of p-toluenesulfonic acid and methanol. Evidence supported a cascade mechanism.

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