Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 23, Pages 9199-9201Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo901822b
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Funding
- BASF, Inc.
- Michigan Economic Development Corp.
- NIH [GM63188]
- ACS Green Chemistry Institute's Pharmaceutical Roundtable
- Pfizer
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Ir-catalyzed C-H borylation is found to be compatible with Boc protecting groups. Thus, pyrroles, indoles, and azaindoles can be selectively functionalized at C-H positions beta to N. The Boc group call be removed on thermolysis or left intact during subsequent transformations.
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