Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 10, Pages 3894-3899Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo900182x
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Funding
- National Science Foundation
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A new aqueous-compatible photoinduced electron transfer based photolabile protecting group has been developed for the release of carboxylic acids. The reduction potential of this group is more positive than previous systems, thereby allowing the use of sensitizers with modest oxidation potentials. Release of several carboxylic acids has been demonstrated using tris(bipyridyl)ruthenium(II) as both a direct sensitizer and a mediator for electron transfer between a good donor and the protecting group.
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