Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 1, Pages 283-288Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo802036m
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- NSFC [20572072, 20632030, 20825207]
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Enantiopure tetra-ortho-substituted biphenyl phosphinoimine ligands (R-a,S)-3 and (S-a,S)-3 were synthesized via multistep reactions. The first asymmetric addition reactions of arylboronic acids to N-benzylisatin catalyzed by Pd(OAC)(2) and (R-a,S)-3 were Studied to provide 3-aryl-3-hydroxyoxindoles in moderate yields and enantioselectivities.
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