Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 14, Pages 5087-5089Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo9006514
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Funding
- National Natural Scientific Foundation of China [20633010, 20773106]
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Catalyzed by Lewis acid, 1,2-diphenyldiselane or 1,2-di-p-tolyldisulfane could add to methylenecyclopropanes smoothly. Compared with the reported free radical additions, the results were quite different. A four-membered carbon ring was constructed to give cyclobutane-1,1-diylbis(phenylselane) derivatives or cyclobutane-1,1-diylbis(p-tolylsulfane) derivatives as products, which are useful intermediates in organic synthesis.
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