4.7 Article

Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 20, Pages 7986-7989

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo901513v

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Funding

  1. JSPS

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alpha,beta-Unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl enolates.

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