Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 11, Pages 4408-4410Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo900417m
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Funding
- National Natural Science Foundation of China [20802076, 20873145]
- Knowledge Innovation Program of the Chinese Academy of Sciences [DICP-S200802]
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An enantioselective synthesis of optically active 1-aryl or 1-alkyl substituted ethylphosphonates, based on the first Rh-catalyzed asymmetric hydrogenation of corresponding alpha,beta-unsaturated precursors with a P-stereogenic BoPhoz-type ligand under the mild condition, was developed, in which a wide range of 1-aryl or 1-alkyl substituted ethylphosphonates were achieved in up to 98% ee.
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