Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 3, Pages 1353-1355Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo802475x
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- EaStCHEM (The Edinburgh and St. Andrews Research School of Chemistry)
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In the presence of stoichiometric magnesium halides, a range of bis-activated cyclopropenes undergo highly stereoselective ring-opening reactions to produce multi substituted alkenyl halides. More highly functionalized compounds may be obtained by trapping of the magnesium enolate intermediates in situ.
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