Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 15, Pages 5633-5635Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo900790k
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Funding
- National Science Foundation of China [20872140, 20621063]
- Chinese Academy of Sciences
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Using pd(cf(3)co(2))(2)/(S,S)-f-Binaphane as the catalyst, an efficient enantioselective Synthesis of sultams was developed via asymmetric hydrogenation of the corresponding cyclic imines with high enantioselectivities. The hydrogenation products can be conveniently transformed to chiral homoallylic amines without loss of enantioselectivity.
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