Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 24, Pages 9570-9572Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo902160y
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- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
- Deutsche Akademische Austauschdienst
- Alexander von Humboldt Foundation
- Young University Teachers of the Alfried Krupp von Bohlen und Halbach Foundation
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An efficient copper-catalyzed intramolecular arylation of formamidines forming 2-unsubstituted benzimidazoles in excellent yields is reported. Sixteen examples bearing sterically demanding substituents on nitrogen like Mes, 2,6-diisopropylphenyl, or 2-tert-butylphenyl and tolerating various functional groups demonstrate the utility of this method.
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