Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 24, Pages 9535-9538Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo901764u
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- National Science Foundation [NSF-CHE-0418902]
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The reduction of carbon-carbon multiple bonds in alkynes and olefins supported on a polystyrene resin has been investigated. Homogeneous catalysis by titanocene reagents is effective for the stereoselective preparation of cis-olefins from diarylacetylenes, while the use of copper(I) hydride reagents is effective for the reduction of alpha,beta-unsaturated ketones.
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