Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 74, Issue 22, Pages 8862-8865Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo9016138
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- American Chemical Society Petroleum Research Fund through the Green Chemistry Institute
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Hydantoins can be synthesized from the corresponding amino amides employing oxidative catalytic carbonylation using W(CO)(6) as the catalyst, I-2 as the oxidant, CO as the carbonyl source, and DBU as base. Secondary amides afford the hydantoins in good to excellent yields, which decrease as the steric bulk of the N-alkyl substituent increases.
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